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  • Articles: DFG German National Licenses  (4)
  • Electronic Resource  (4)
  • 1995-1999  (4)
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  • Articles: DFG German National Licenses  (4)
Material
  • Electronic Resource  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 62 (1996), S. 457-464 
    ISSN: 1432-0649
    Keywords: 42.79
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A commercially available neon indicator lamp in a Relaxation Oscillator (RO) configuration has been demonstrated to be capable of detecting light intensities of the order of nanowatts under ambient light conditions with a subpicometer spectral resolution. The RO has also been shown as capable of acting as a wireless light switch with light intensities of the order of 1 µW. Temporal excitation studies have also shown the predominant mechanism describing the observed frequency changes in the RO to be a result of laser perturbation of the neon lamp when it is in the Townsend-discharge region and not in the abnormal glow.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 355 (1996), S. 227-232 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The application of laser-based techniques to the study of different problems related to atmospheric chemistry is well established. Among the various laser spectroscopic methods, the focus here is directed towards selected applications of the laser photofragmentation and fluorescence techniques, which are used to investigate the complex chemistry of tropospheric sulphur species, with particular emphasis on the oxidation of dimethyl sulphide (DMS) and the consequent formation of sulphuric acid, and to the possibility of detecting with very high sensitivity and selectivity a particular element (e.g., gold) in size-segregated aerosol particles in view of its possible release as a tracer in the atmosphere. The atomic fluorescence technique is also applied to the real time detection of lead in a miniature air-acetylene flame, in which monodisperse aerosol particle are introduced.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 356 (1996), S. 21-26 
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract An experimental set-up for the detection of elemental chlorine in chlorinated hydrocarbons (CHCs) is described based on a miniaturized system, which could be used for on-line monitoring of chlorinated compounds. With an optimized time-resolved detection chlorine from CHCs like CCl4 can be determined by Laser-Induced-Breakdown-Spectroscopy (LIBS) with μg/g-detection limits in the gas phase. The application of a miniaturized Nd : YAG laser resulted only in a minor loss in performance, hence it could be used for designing a rugged and small on-line sensor. In addition, preliminary results for the detection of chlorine via the formation of CuCl in the plasma formed by focussing the laser on a copper surface are reported. Utilizing the luminescence of the CuCl D-system at 440 nm, a tenfold improvement in the detection limits was obtained. It appears that the formation of “ad hoc” selected, small molecules in a laser plasma could be a promising alternative for the selective and sensitive analysis of gaseous chlorinated and other species.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A method is described for measuring the gold content of integral and size-segregated samples of atmospheric particulate matter. After acid digestion and a liquid/ liquid extraction, the sample are analysed by Two-Colour Laser Induced Fluorescence in a graphite furnace. An absolute instrumental detection limit of 1 fg is achieved. Assuming a sampled volume of 1 m3, this corresponds to an atmospheric concentration of 50 fg m–3. Due to blank limited noise, the above limits increase to 20 fg and 1 pg m–3, respectively. Results of the analysis of filter samples as well as of size-segregated impactor samples are presented.
    Type of Medium: Electronic Resource
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