ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
13C and 15N spectroscopies at natural abundance have been applied to the study of nitrogen lone-pair delocalization in N—N containing compounds: nitrosamines, nitramines, hydrazines, hydrazones and triazenes. Structure-chemical shift correlations have been derived for nitrosamines; the 13C upfield effect of a γ substituent has been used for assigning the configuration of both diastereoisomers in N,N-unsymmetrically substituted nitrosamines. Equations have been computed which permit the prediction of the electronic delocalization, expressed in terms of free enthalpy of activation ΔG≠298, as a function of δ15N and of the length of the N—N bond. 15N spectroscopy has also been applied to the study of the protonated species of nitrosamines and of acceptor-donor complexes of nitrosamines with Lewis acids. The behaviour of such N—N containing compounds is compared to that of amides.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270120502
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