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  • Articles: DFG German National Licenses  (46)
  • 1970-1974  (46)
  • 1970  (46)
  • Chemical Engineering  (46)
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 10 (1970), S. 241-246 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The results of a study to determine the biological stability of clear, colorless, biocide-treated PVC film are presented. With the exception of a resistant control, all the PVC film samples tested contained a plasticizer susceptible to biological deterioration. Biocide-treated and control PVC film samples were subjected to biological attack in soil burial. Portions of each sample were exposed to leaching and to weathering in a weatherometer followed by soil burial to test the stability of each biocide to loss by water and weathering exposure. Of the 32 biocide preparations tested only 2, N-(trichloromethylthio) phthalimide and copper 8-quinolinolate, a known effective reference compound, were found to provide good protection for treated film in direct soil burial and in soil burial following leaching and weatherometer exposure. Natural weathering outdoors confirmed the results found with weatherometer exposed samples. The N-(trichloromethylthio) phthalimide was less effective than the reference compound in suppressing surface growth. In addition, N-(trichloromethylthio) phthalimide may not be compatible with all PVC formulations.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 249-254 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The hydrolysis of acetyl chloride was studied in a laboratory reactor designed to act as a chemical oscillator. The observed oscillating outputs are in fairly good agreement with the numerical solutions of the stirred tank reactor equations and the approximate analytical solutions published previously.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 108-111 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Tray efficiencies were measured for desorbing ammonia from water by air in a small sieve-tray column operated in the cycling mode, that is, with alternate flow of vapor and liquid. The actual efficiency improvement obtained was compared with that theoretically possible assuming the liquid flows without mixing when dropped. A mixing model was proposed and the mixing parameter evaluated from the experimental data.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 553-559 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study of the photochlorination of propane was undertaken to assess the significance of heterogeneous termination steps (wall reactions). Data were obtained in 2- and 10-mm. I.D. tubular flow reactors with varying oxygen concentrations. The results indicated that homogeneous terminations were dominant in the large reactor, and heterogeneous ones were dominant in the small unit. A kinetic scheme which explained the data was proposed. It included two parallel termination steps: a second-order homogeneous reaction between C3H7. and oxygen and a first-order heterogeneous reaction between C3H7. and the reactor wall.Even though the data were taken in the laminar flow regime, the rate of reaction was a function of Reynolds number for the 10-mm. reactor. Kinetic factors may explain these results, but the reasons are not clear. More research in this area is needed.Data taken in the 10-mm. reactor packed with quartz cylinders gave results similar to those for the 2-mm. reactor. This provided confirming evidence for the proposed scheme of parallel, heterogeneous and homogeneous termination steps.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 588-594 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The heat and mass transfer processes in a binary mixture flowing in a parallel plate channel with mass addition at the bounding surfaces are investigated analytically. The rate of mass addition, the temperature, and the mass fraction are arbitrarily prescribed at each of the bounding walls. Similarity solutions are evaluated numerically to yield pressure gradient, Nusselt number, and Sherwood number results for a wide range of each of three governing parameters. It is found that increasingly strong surface mass addition markedly increases the magnitude of the axial pressure gradient. Mass addition decreases the Nusselt and Sherwood numbers at the channel wall at which the injection is strongest but may actually increase these moduli at the opposite wall. A generalizing analysis is performed to accommodate phase change processes as well as to accommodate the specification of plenum conditions rather than wall surface conditions. Application is made to the evaporation of liquid water by an air stream. It is shown that the rate of evaporation is augmented as the rate of air injection increases, but the extent of the augmentation is less than the causative increase in the air flow rate.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 633-638 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A previous report (1) has presented the derivation of new filter cake washing equations. This report presents the procedure for their application and contains an example of application to a specific batch washing system. It also presents the adaption of the equations to permit their use in predicting the performance of a continuous rotary-drum filter.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 832-837 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Ternary diffusion coefficients at 25°C. of the system 0.5 g./cc. d-tartaric acid - 0.5 g./cc. l-tartaric acid-water are reported. The results allow experimental verification of the theory for the diffusion of two indistinguishable solutes and clearly illustrate the difference between mutual and tracer diffusion. Moreover, the results allow calculation of ternary mass transfer coefficients and ternary tray efficiencies for the case of two similar species dissolved in a third.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 882-884 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 1064-1071 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The photodecomposition of aqueous solutions of formic acid was studied as a model reaction for removing organic pollutants from water. The process was carried out in a tubular-flow reactor, operated continuously. The cylindrical reactor was irradiated from the outside by placing the cylindrical lamp and the reactor at the foci of an elliptical reflector. Measurements made at differential operating conditions permitted calculation of rates of reaction as a function of formic acid concentration and light intensity for the temperature range 25° to 60°C. Carbon dioxide and carbon monoxide were the only observed products of the decomposition.The rate was first order in absorbed light intensity and between zero and first order in formic acid. These results correspond to a combination of chain and non-chain kinetics occurring simultaneously. Rate constant ratios and quantum yields were calculated from the data and the kinetics model.A few measurements were made by adding ferric chloride and ferrous chloride to the feed to the reactor. An order of magnitude increase in rate was observed with these sensitizers.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 90-96 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Exact solutions of the boundary layer equations were used to calculate the local mass transfer coefficients for an impinging jet with a parabolic velocity distribution. Boundary conditions were obtained from an inviscid flow solution and also from experimental pressure distributions. Experimental data for the air/naphthalene system were in good agreement with theoretical results. Mass transfer from the impingement surface was independent of nozzle height in the range 0.5 to 12 nozzle radii. For lower nozzle heights the effect of the constriction of flow between the nozzle and the surface led to increased transfer rates near the nozzle wall; data followed the predicted behavior.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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