Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
107 (1997), S. 2419-2423
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Using the photoelectron–energy-selected photoion coincidence technique, we find that photoions of BF3 with kinetic energy larger than 4 eV are predominantly F+ in the F 1s ionization region whereas B+ is more intense than F+ at the F 1s→2a2″ excitation. Two partial cross sections σ|| and σ⊥ for A1′→E′ parallel and A1′→A2″ perpendicular transitions are obtained from the angular distribution measurement of energetic photoions and the symmetries of some F 1s core excited states are confirmed. The dissociation dynamics of the F 1s−12a2″ core excited state are discussed in detail. © 1997 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.474585
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