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  • Articles: DFG German National Licenses  (71)
  • 2000-2004  (47)
  • 1995-1999  (24)
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  • Articles: DFG German National Licenses  (71)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 85 (1999), S. 4491-4493 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A glass transition, followed by a supercooled liquid region was found in wide composition ranges of 0–65 at % Co and 1.5–7 at % Ln in Fe80−x−yCoxLnyB20 (Ln=Nd, Sm, Tb, or Dy) amorphous alloys. The supercooled liquid region (ΔTx) shows the largest value of 41 K for the Fe47Co30Sm3B20 alloy. An internal equilibrium state leading to the disappearance of the previous thermal history was achieved within a temperature interval of 15 K. The Fe–Co–Ln–B amorphous alloys exhibit soft ferromagnetism with saturated magnetization (Bs) of 0.84–1.66 T and coercivity (Hc) of 5.0–36 A/m. A high magnetostriction (λs) exceeding 40×10−6 was also observed in the composition range of 0–10 at % Co and 1.5–3 at % Ln (Ln=Sm, Tb, or Dy). The highest λs reaches 58×10−6 for Fe68.5Co10Ln1.5B20 (Ln=Sm or Tb), which is higher than the highest value (44×10−6) for previously reported amorphous alloys. All the Fe68.5Co10Ln1.5B20 amorphous alloys have good bending ductility. The tensile strength, Vickers hardness and Young's modulus of the Fe68.5Co10Sm1.5B20 alloy are 3220 MPa, 990 and 76.5 GPa, respectively. The combination of high λs, high Bs, low Hc, large ΔTx, good ductility and high mechanical strength is promising a new type of ferromagnetic bulk amorphous alloy. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 67 (1995), S. 2008-2010 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report the production of full strength compacts of metallic glass by warm extrusion of powders at the supercooled liquid state just above the glass transition temperature. The alloy used was Zr65Al10Ni10Cu15 (at. %) which has the lowest viscosity among Zr-based metallic glasses with large supercooled liquid region. The tensile strength and Young's modulus of the glassy powder compacts were 1520 MPa and 80 GPa, respectively, which are similar to that obtained in the as-cast bulk alloy and melt-spun ribbon. This opens up possibilities of producing high strength amorphous alloys with complex shapes. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 340-342 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Nanocrystalline composites with the grain size less than 10 nm were produced by annealing of Cu-mold cast Zr70−x−yTixNi10Cu20Aly (X=5–7.5 and Y=10–15 at %) bulk amorphous alloys. The nanostructured alloys show increased tensile strength at the volume fraction of nanoparticles less than 30%. The microstructure of the amorphous alloys was found to contain medium range order (MRO) domains, which uniformly distributed in the amorphous matrix. We suggest that MRO domains provide nucleation sites for precipitation of the primary crystals and lead to the formation of nanocrystalline composites. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 3644-3646 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapidly solidified ribbons of nanocrystal-forming Zr–Cu–Pd–Al metallic glasses were prepared at various liquid temperatures (TL). Differential scanning calorimetry (DSC) traces show clearly the influence of the liquid states on the thermal properties and crystallization process. Namely, with increasing TL, the exothermal peaks of the DSC traces shift to higher temperatures, the super-cooled-liquid region ΔTx increases, and the decomposition of the metastable compound Zr2(Cu, Pd) becomes more difficult. These results suggest that the liquid state strongly controls the crystallization process of the nanocrystal-forming metallic glasses. This behavior may originate from the variation of the quenched-in nuclei, which highly depends on the short-range-order domains in liquid with different TL. We suggest that the stronger attractive interaction in Zr–Pd, which exhibits large negative mixing enthalpy, leads to the short-range order domains. © 1999 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We have found that an amorphous phase with a wide supercooled liquid region reaching 85 K before crystallization is formed in Fe–(Co, Ni)–(Zr, Nb, Ta)–B, Fe–Co–(Zr, Nb)–(Mo, W)–B and Co–Fe–Zr–B systems. The high stability of the supercooled liquid enabled the production of bulk amorphous alloys with diameters up to 5 mm by copper mold casting. These amorphous Fe–(Co, Ni)–M–B alloys exhibit good soft magnetic properties, i.e., saturation magnetization of 0.95 to 1.1 T, low coercivity of 1 to 8 A/m, Curie temperature of 560 to 590 K and low magnetostriction of 8–14×10−6. The effective permeability of the Co–based alloys exceeds 25 000 at 1 kHz and keeps high values above 5000 at the high frequency of 1 MHz. The permeability at 1 MHz is much higher than those for any kinds of soft magnetic materials. The frequency at which the imaginary part of permeability shows a maximum is also about 1 MHz. The success of synthesis of new Fe- and Co-based amorphous alloys with good soft magnetic properties and high glass-forming ability is promising for future development of a new type of soft magnetic material. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 80 (2002), S. 1556-1558 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: In this letter we compare the glass-forming capabilities of binary Si,Ge–Ni and ternary Si,Ge–Ni–Nd alloys. The addition of Nd caused the formation of an amorphous single phase in the Ge–Ni–Nd alloy. The structure and crystallization behavior of the amorphous alloy were studied by differential scanning calorimetry and x-ray diffractometry. No amorphous phase formed in any of the Nd-free alloys or in the Si–Ni–Nd alloy. The higher glass-forming capability of the Ge–Ni–Nd alloy compared to Si–Ni–Nd cannot be explained on the basis of the widely used geometrical and chemical factors, viscosity, or diffusion data. The importance of the electronic structure characteristics is suggested to be a reason. © 2002 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 1114-1116 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The Newtonian viscosity of the supercooled liquid measured by the continuous-strain-rate tensile test was investigated in the Pd40Ni40P20 metallic glass. It was found that continuous-strain-rate tests were applicable to determine the viscosity over a wide strain-rate region, and that the measured Newtonian viscosity η0 corresponded to the equilibrium one. The viscosity η over the entire strain-rate interval could be well described by one master curve expressed with a stretched exponential function η/η0=1−exp(C/cursive-epsilon(overdot)β) in which β was 0.82. The free-volume-theory relation proposed by Cohen and Grest reproduced the equilibrium viscosity data over the entire temperature region better than the famous Vogel–Fulcher–Tammann relation. The supercooled liquid of the Pd40Ni40P20 metallic glass was classified into the relatively strong liquids as well as the other metallic glasses. The Pd40Ni40P20 metallic glass that is a metal-metalloid alloy exhibited to be more fragile than metal–metal glasses. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 77 (2000), S. 46-48 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Mechanical properties of bulk Zr60Cu20Pd10Al10 nanocrystalline composite and Zr55Ni5Cu30Al10 metallic glass were measured by compression tests at room temperature. The Zr60Cu20Pd10Al10 as-quenched alloy obviously exhibits plastic strain while no distinct plastic deformation is recognized in the Zr55Ni5Cu30Al10 metallic glass. Moreover, the plastic strain increased by increasing the volume fraction of nanocrystals and achieved maximum value in the early stage of the nanocrystallization. High-resolution electron microscopy showed that, different from the microstructure of Zr55Ni5Cu30Al10 metallic glass, nanocrystals with main grain sizes of about 2 nm were embedded in the amorphous matrix of the bulk Zr60Cu20Pd10Al10 alloy which showed the maximum plastic strain. © 2000 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 79 (2001), S. 1792-1794 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Rapidly solidified ribbons from the nanocrystal-forming Zr60Cu20Pd10Al10 alloy prepared at various melting liquid temperatures were used to study the influence of the liquid state upon quenched-in nuclei. With lowering quenching liquid temperatures, the small-angle x-ray scattering shows increased related periodic composition fluctuations and the radial distribution function analysis from x-ray diffraction method reveals that the coordination number of Pd around Zr increases. These results provide evidence for the stronger attractive interaction in Zr–Pd, which exhibits large negative mixing enthalpy, leads to the formation of (Zr, Pd)-rich domains of short-range order in the liquid. They remain in the amorphous phase as quenched-in nuclei and therefore contribute to nanocrystalline formation. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 3061-3063 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The present letter aims to report the effect of supercooled liquid region on crystallization behavior of an Al85Ni5Y4Nd4Co2 metallic glass produced by rapid solidification of the melt. It is found that crystallization behaviors of this alloy above and below the glass-transition temperature are completely different. Formation of the primary nanoscale α-Al particles observed during continuous heating or after annealing above glass-transition temperature does not occur during isothermal annealing below glass-transition temperature when an unidentified intermetallic compound, and α-Al phases are formed simultaneously. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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