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  • Articles: DFG German National Licenses  (1)
  • 2000-2004  (1)
  • europium  (1)
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  • Articles: DFG German National Licenses  (1)
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  • 2000-2004  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of sol gel science and technology 19 (2000), S. 357-360 
    ISSN: 1573-4846
    Keywords: photoreduction ; europium ; inorganic-organic hybrid material ; ligand
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Eu2+-doped inorganic-organic hybrid materials, which are potentially suitable for a tunable laser in the near ultra violet and blue region, were prepared through the photoreduction of Eu3+ ions in the materials under the irradiation of the fourth harmonic wave light (266 nm) of the Nd:YAG laser. The hybrid materials doped with Eu3+ ions were prepared from Si(OCH3)4, CH3Si(OCH3)3, EuCl3 and chloropropyltrimethoxysilane (CPTM). After the prehydrolized silica sol was added to the Eu3+-containing solution, Eu3+-doped transparent inorganic-organic hybrid material was obtained by drying at 50°C. The emission peak around 450–475 nm due to the charge transfer transition (5d-4f) of Eu2+ ions increased with the laser irradiation time. Eu3+ ions were effectively photoreduced to Eu2+ ions in pore-free materials prepared at high CPTM to Eu3+ ratios. Eu2+ ions were generated by the photodecomposition of the bond between Eu3+ and Cl (Cl− or Cl(CH2)3 in CPTM).
    Type of Medium: Electronic Resource
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