ISSN:
1434-6036
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Physik
Notizen:
Abstract. X-Ray Magnetic Circular Dichroism experiments have been conducted on a vanadium inorganic salt and a vanadium enamino-ketone complex. Measurements at the K edge of oxygen and nitrogen reveal the amount of magnetic moment transferred in the 2p orbitals of the ligand atoms from the magnetic V ion. Measurements at the L edge of vanadium show that the orbital moment is small and that J = L + S, contrary to the expected J = L-S coupling for a 3d metal with less than five d-electrons. This surprising inobservance of Hund’s third rule emphasizes the need for more detailed studies and calculations on such hybrid molecules.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1140/epjb/e2004-00097-9
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