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Synthesis, Reactivity, and Molecular Structures of Bis(diphenylphosphanyl)amine- and Bis(diphenylphosphanyl)amide-Bridged Heterobimetallic μ-Isonitrile- and μ-Aminocarbyne Complexes (Fe-Pt) (1998)

Knorr, Michael ; Strohmann, Carsten

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 495-499

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ISSN: 1434-1948

Keywords: Heterobimetallics ; μ-Isonitrile complexes ; μ-Aminocarbyne complexes ; Bis(diphenylphosphanyl)amine ; Iron ; Platinum ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Addition of isonitriles to [(OC)3Fe(μ-CO)(μ-Ph2PNHPPh2)Pt(PPh3)] 1 produces the μ-isonitrile complexes [(OC)3Fe(μ-C=NR)(μ-Ph2PNHPPh2)Pt(PPh3)] 2, which are transformed to the μ-aminocarbyne complexes [(OC)3Fe{μ-CN(El)R}(μ-Ph2PNHPPh2)Pt(PPh3)]+;3 and 4 by electrophilic addition of [El][BF4] or [El][OSO2CF3] (El = H, Me). The dppa backbone of 4 is readily deprotonated by KOSiMe3 to yield the very stable zwitterionic aminocarbyne complex [(OC)3Fe{μ-CN(Me)2,6-xylyl}(μ-Ph2PNPPh2)Pt(PPh3)] 5.

Type of Medium: Electronic Resource

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