ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The hydrothermal reaction of MoO3, V, Na2WO4· 2H2O, [N(CH2CH2)3N](1,4-diazabicyclo[2.2.2] octane), and H2O at 160°C for 90h gave dark-brown crystals of [HN(CH2CH2)3N]2[HMoVMoVI 5O19]·[N(CH2CH2)3N], (1), in 40% yield. Complex (1) is the first one-electron reduced mixed-valence hexamolybdate to be crystallized and structurally characterized. The crystal structure of (1) consists of discrete [HMoVMoVI 5O19]2− anions, [HN-(CH2CH2)3N]+ cations, and neutral [N(CH2CH2)3N] molecules of crystallization.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1006973821956
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