ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Fluoro Substituted and other New CarbodiphosphoranesSyntheses and properties of the carbodiphosphoranes [(CH3)2N]3P=C=P(CH3)[N(CH3) 2]2, (3), [(CH3)2N]2(F)P=C=P(F) [N(CH3)2]2, (7), and (C6H5)2(F)P=C=P(F)(C6H5) 2, (11), are discribed. The compounds 3, 7, and 11 as well as [(C2H5)2N]3P=C=P(CH3) [(C2H5)2N]2 are characterized by their 1H, 13C, 19F, and 31P n.m.r. and mass spectra. The crystal and molecular structures of 7 are reported.
Notes:
Synthese und Eigenschaften der Carbodiphosphorane [(CH3)2N]3P=C=P(CH3)[N(CH3)2]2, (3), [(CH3)2N]2(F)P=C=P(F)[N(CH3)2]2, (7), und (C6H5)2(F)P=C=P(F)(C6H5) 2, (11), werden beschrieben. Die Verbindungen 3, 7 und 11 sowie [(C2H5)2N]3P=C= P(CH3)[(C2H5)2N]2 sind durch ihre 1H-, 13C-, 19F- und 31P-NMR-Spektren sowie durch ihre Massenspektren charakterisiert. Die Kristall- und Molekülstruktur von 7 werden mitgeteilt.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19885670104
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