ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The kinetics of the binding of the neurotoxin acrylamide to the cysteine residue of glutathione has been studied. At 37 °C and pH 7.3 the second order rate constant has been determined to be 0.72 ± 0.06 mol-1 dm3 min-1 by thermospray mass spectrometry. The critical energy at pH 11.5 measured over the temperature range 10-37°C by fast atom bombardment mass spectrometry was measured as 24.6 kJ mol-1.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210240828
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