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  • Articles: DFG German National Licenses  (1)
  • 1985-1989  (1)
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  • Articles: DFG German National Licenses  (1)
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    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 85 (1986), S. 3476-3481 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A local HNC/HNC approximation is proposed and applied to 2:2 electrolytes near a charged hard wall. The results are compared with Monte Carlo data and other theories such as HNC/HNC, HNC/MSA, BGY, and MPB5. A remarkable improvement of the density profiles and of the diffuse layer potential is obtained. We show that the HNC closure for the ion–ion correlations, when used in the local scheme, always gives better results than those obtained from the MSA closure. The necessary algorithm for solving the local HNC/HNC equations is also presented.
    Type of Medium: Electronic Resource
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