ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
4-Substituted-1,2,4-triazoline-3,5-diones have been used to synthesize a series of new polydienes by the “ene” reaction at ambient temperatures. The extent of chemical conversion can be varied widely and up to 93% of the diene-repeating units of the parent polymer chain undergo reaction. Yields of the new polymers based on the reactant range from 90 to 95% at room temperature; their physical properties range from secondary crosslinking effects or elasticity at low degrees of conversion to rigid, amorphous polymers with high softening points at high degrees of conversion. The new polymers show a predictable correlation between the extent of conversion and the softening point. A similar correlation exists between the polarity of the new polymers and the extent of conversion. Polydienes with conversions to the extent of 45% or greater are soluble in aqueous solutions of sodium hydroxide and those with conversions of 60% or greater are soluble in aqueous sodium bicarbonate. Thus, in general, the new polymers (1) have higher Tg, (2) become increasingly polar, hence are soluble in polar solvents, and (3) possess a reasonably acidic proton, hence form salts. Bistriazolinediones result in room temperature crosslinking. A kinetic study with model compounds suggests that the rate of the reaction can be varied, depending on the electronic nature of the 4-substituent.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1979.170170416
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