ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A kinetic investigation on the reaction has been carried out in HClO4 medium under different conditions. A spectrophotometric method of estimation of nitrous acid at various time intervals has been employed. The results are interpreted on the basis ofthe following mechanism: The absolute rate constant value of 39.7 M-1 plusmn; s-1 for k4 and the equilibrium constant Keq = 116M-1 for reaction (2) have been evaluated. The activation energy of the overall reaction has also been determined as Ea = 13.2 kcal/mol.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550090411
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