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  • Articles: DFG German National Licenses  (4)
  • 1970-1974  (4)
  • Chemistry  (3)
  • Continuous Temperature Signals  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Pflügers Archiv 345 (1973), S. 43-59 
    ISSN: 1432-2013
    Keywords: Temperature Regulation ; Hypothalamic Thermal Stimulation ; Core Temperature ; Continuous Temperature Signals ; Feedback Control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary In four conscious goats with chronically implanted hypothalamic thermodes, forty-three experiments were carried out at environmental conditions between +5°C and 30°C DB/18°C WB. The temperature of the hypothalamus was altered by perfusing the thermodes with water whose temperature, as measured at the inlet of the thermodes, varied between 30°C and 43°C. Heat production, respiratory evaporative heat loss, rectal and oesophageal temperatures were measured. Hypothalamic cooling resulted in an elevation of rectal temperature, while hypothalamic heating caused a fall in temperature. The relation between the intensity of hypothalamic thermal stimulation and the induced change in core temperature can be well described by linear regressions. No difference in sensitivity and no dead band between responses to cold and warm stimulation was found. The experiments show that hypothalamic and extra-hypothalamic sensors of core temperature continuously operate at high sensitivity even within the narrow range of physiologically occurring core temperatures. Qualitatively, this sensitivity is independent of air temperatures between +5°C and +30°C.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 16 (1970), S. 254-260 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An experimental study was made on the breakup of a single drop in two phase liquid-liquid developing turbulent pipe flow. The predominant breakup mechanism was controlled by dynamic pressure forces, and the drop breakup was characterized by one or two smaller drops breaking off a larger drop.The effect on the increase in interfacial area and the resulting size distribution of the fragmented drops of drop velocity, interfacial tension, initial drop size, and the distance down the pipe was studied. Regression analysis was used to determine the significant effects. Most of these regression equations had significant cubic and two-factor interactions, which is indicative of the complexity of drop breakup.The size distribution of the fragmented drops can be approximated by a normal distribution. However, the steady state distribution was not fully developed in the work here.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectral data for the primary fragmentation of partially ethylated alditol acetates have been tabulated in order to allow easy reference for the identification of these polysaccharide derivatives. Sodium borodeuteride is used in all the aldose to alditol reductions, since the presence of a single deuterium label on C-1 greatly increases the information available in the mass spectrum and allows some identifications to be made which would not otherwise be possible. The primary fragmentations of these derivatives are analogous to those of the partially methylated alditol acetates, with each fragment shifted to a higher m/e value by fourteen mass units for each ether linkage contained in the fragment. The secondary fragmentation is also very similar, being characterized by the loss of acetic acid or ketene, or, less frequently, by the loss of ethanol or acetaldehyde. Coupled with the chromatographic retention time data for the partially ethylated alditol acetates tabulated elsewhere, the unambiguous mass spectral identification makes this derivative an excellent choice as a complementary derivative to the partially methylated alditol acetates for polysaccharide analysis. The utility of the partially ethylated alditol as a routine analytical derivative is further enhanced by the almost identical procedures required for synthesis of the ethyl and methyl derivatives. Through the combined use of these derivatives, most of the possible linkage isomers of the seven common aldoses of plant cell wall polysaccharides can be resolved, identified and quantitated.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 16 (1972), S. 1701-1720 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The temperature dependence of mechanochemical reactions of high polymers is investigated in light of viscous dissipation in the flow field. The viscosity of the polymer melt is assumed to depend exponentially upon temperature, and the power-law model is used to describe the shear stress-shear rate relationship. Using equations previously reported in in the literature for the temperature profile generated in capillary flow, evidence that such an experimental system operates under decidedly nonisothermal conditions is presented. These equations, together with the classical Arrhenius equation for the temperature dependence of chemical reactions, predict that the average reaction rate in a capillary decreases, passes through a minimum, and increases as the capillary wall temperature is increased. Good agreement exists between the temperature at the minimum rate found in this work and that found experimentally for polystyrene, natural rubber, and polyisobutylene.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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