ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Synthesis and Properties of Bis(dialkylamino)methylarsinesThe reactions of secondary amines with CH3AsJ2 lead to the formation of Bis(dialkylamino)methylarsines. Ten arsines have been prepared by this method and are described. IR and 1H-NMR and mass spectral data are presented for these compounds and discussed.Acid molecules cleave the As—N bond. The reactions with halogen hydrides, water, alkoholes, thioles and amines are described.
Notes:
CH3AsJ2 setzt sich mit sekundären Aminen zu Bis(dialkylamino)-methylarsinen um. Zehn Arsine wurden dargestellt und beschrieben. IR- und 1H-NMR- und Massenspektren werden mitgeteilt und diskutiert. Die Aminoarsine reagieren mit H-aciden Molekeln (Halogenwasserstoffen, Wasser, Alkoholen, Thiolen) unter Spaltung der As—N-Bindung.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19733970202
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