ISSN:
1436-5073
Keywords:
FT-IR spectra
;
thiocyanate complex
;
crown ether
;
2,2′-bipyridyl
;
transition metal
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A series of new transition metal complexes with the thiocyanate ion: (1) Mn(NCS)2·Benzo-15-crown-5, (2) Mn-(bipy)(NCS)2, (3) Ni(bipy)(NCS)2, prepared by using solution reaction methods, have been characterized by FT-IR spectra. The expression (I 2/I 1=tan2 θ) has been suggested to be used to calculate the bond angle N-metal-N (N atoms come from the two coordinating NCS groups) in the complexes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01205874
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