ISSN:
0009-2940
Keywords:
Alane, amino-
;
Aluminium nitride
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reactions of hydrazine with tris(trimethylsilyl)aluminium-ether have been studied: Reactant ratios of 0.5:1 and 0.8:1 produce the cyclic aminoalane [(Me3Si)2AlN(H)(SiMe3)]2 (1), which is formed by N-N bond cleavage and silyl group migration from aluminium to nitrogen. Pyrolysis under NH3 of a polymeric product formed from a 1:1 reaction produces an AlN/Si3N4 composite.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931261213
Permalink