ISSN:
1040-0397
Keywords:
Nickel
;
Adsorptive stripping voltammetry
;
Dimethylglyoxime
;
Optimization
;
Experimental design
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A procedure for the determination of nickel by adsorptive stripping voltammetry (AdSV), using dimethylglyoxime as complexing agent, has been optimized. The determination was carried out by two different techniques: differential pulse adsorptive stripping voltammetry (DPAdSV) and square wave adsorptive stripping voltammetry (SWAdSV). The selection of the experimental parameters was done using a factorial design which allows one to find the most significant variables, i.e., those which exert the greatest influence on the measured magnitude, with a reduced number of experiments. Posterior optimization of these variables provided the most adequate experimental conditions and it was under these conditions that the calibrations were made, using a robust regression method which allows the elimination of anomalous points.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/elan.1140080315
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