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  • Articles: DFG German National Licenses  (4)
  • Chemistry  (4)
  • 1
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A brief introduction describes the main differences between homo, and copolymer polyacetals and their main degradation mechanisms. A short overview describes the importance of stabilization and the necessity of using antioxidants and costabilizers during manufacturing, processing and end use of polyoxymethylene(polyacetals). Various stabilizer systems are presented and studies on the interaction of antioxidants with costabilizers added. The criteria for testing the performance of these additives are discussed and demonstrated by many examples.In a second part the increasing importance of light stabilized polyacetal is mentioned and investigations on the performance of light stabilizer systems are highlighted.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: After a few general remarks with regard to degradation of polyurethanes under the influence of light, some new results considering the stabilization of such systems will be treated. Apart from a comparison between aromatic and aliphatic one component systems for textile coating, the main subject of this paper is the light stabilization of integral-PUR foams as well as the stabilization of thermoplastic polyurethane. New fully liquid systems as light stabilizers for PUR may be of special interest.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 17 (1988), S. 399-404 
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A gas chromatographic/mass spectrometric procedure has been developed for the quantification in plasma of dideoxycytidine (DDC), a candidate anti-AIDS drug. The assay uses an extraction with ethyl acetate containing 10% methanol followed by three derivatization steps: (i) reaction with t-butyl dimethyl chlorosilane to silylate the 5′-hydroxyl group; (ii) pentafluorobenzoylation of the amino group with pentafluorobenzoyl chloride; (iii) methylation of the ring nitrogen adjacent to the amino group with diazomethane. The resulting derivative is quantified using stable isotope dilution, selective ion monitoring and methane negative chemical ionization mass spectrometry. Plasma concentrations of DDC were measured over a range of 2-200 ng ml-1 using 1 ml plasma for extraction.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The stabilization of polyamides or nylons, considered the oldest engineering plastics, has been the subject of many patents in the last 50 years. Most of these patents refer to attempts to improve the resistance of polyamides against the negative influence of heat and oxygen. Light stability, however, was always of certain interest as well, and more so in recent years when polyamide producers started to search seriously for new fields of application.Some general remarks will be made on how to test the heat stability of this substrate group. The three different types of heat stabilizing systems with their advantages and disadvantages will be discussed briefly. Among these three systems - copper halides, secondary aromatic amines and phenolic antioxidants - the latter will be dealt with in some depth.Some information will cover investigations on stabilization of polyamides in general. Another study will be presented that deals with the behavior of polyamide 6 at various elevated temperatures. The results of an extraction of polyamide 66 with boiling water will be explained including discussion of the consequences.An example will also be given for the heat stabilization of polyamide 12.Some general remarks on testing polyamides under the influence of light lead to several considerations concerning light stabilizer systems for polyamides. Examples will be given for polyamides 6, 66 and 12.A short survey of the status quo with regard to polyamide stabilization and an outlook for the future will conclude this paper.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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