ISSN:
0009-2940
Keywords:
Dioxasilirane/Silylene oxidation/Matrix isolation
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of difluorosilylene and dichlorosilylene with molecular oxygen in Ar matrices has been investigated. Under the reaction conditions the silylenes proved to be of low thermal reactivity, and irradiation in the UV/VIS was necessary to produce difluorodioxasilirane and dichlorodioxasilirane, respectively. The IR spectra have been assigned by isotopic labelling and by comparison with ab initio calculations.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230119
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