ISSN:
0935-6304
Keywords:
Chromatographic behavior HPLC & GC
;
Coupled HPLC-CGC
;
Concurrent solvent injection
;
500 μl injection in CGC
;
Methylated dibenzothiophenes
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Concurrent solvent evaporation with a loop-type interface was used for on-line HPLC-CGC in the analysis of methylated dibenzothiophene (DBT) isomers in oil samples. The chromatographic behavior of 20 methyl DBT's was studied by HPLC on an aminopropylsilane DBTA phase and by GC on a selective methyl-phenylsilicone phase. That provided a method for analyzing by GC-flame photometric detection, the individual components of the DBT family, previously picked out of the crude oil matrix by HPLC. The GC oven temperature was shown to be critical during HPLC eluent introduction into the GC pre-column. Too high a temperature induced a severe broadening of early eluted peaks whereas a temperature too close to the boiling point of the liquid at the inlet pressure induced double peaks. Optimized conditions were retained on this basis and may be used for the analysis of other families of polyaromatic hydrocarbons.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jhrc.1240111005
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