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  • Artikel: DFG Deutsche Nationallizenzen  (8)
  • Fluorescent dyes  (7)
  • Decarboxylation  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 1915-1917 
    ISSN: 1434-193X
    Schlagwort(e): Cyclophanes ; Fluorescent dyes ; Perylenes ; Exciton coupling ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Dynamic processes, a bathochromically shifted fluorescence, and strong solvent-induced chirality effects are observed for the [12,12]-perylene-bis(imide)-cyclophane 3, which forms a “fixed supramolecule”.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 2000 (2000), S. 365-380 
    ISSN: 1434-193X
    Schlagwort(e): Fluorescent dyes ; Perylenes ; Heterocycles ; NIR dyes ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: ---Core-extended perylenetetracarboxylic bisimides were prepared by Diels-Alder reaction followed by reduction, or by nitration followed by cyclisation. Highly fluorescent dyes were obtained with absorption regions from the visible to the NIR. Applications for solar energy harvesting, and quantum counters were suggested.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 847-851 
    ISSN: 1434-193X
    Schlagwort(e): Fluorescent dyes ; Perylenes ; Heterocycles ; Carboxylic acids ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis and properties of perylene-bisimides 4 with one carboxylic acid anchor group are described. The properties of 4 are strongly influenced by the spacer between the carboxylic acid group and the imide moeity. Dyes with aliphatic (4d-4g) and aromatic (4a-4c) spacers have been prepared.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1996 (1996), S. 1587-1591 
    ISSN: 0947-3440
    Schlagwort(e): Perylenes ; Heterocycles ; Fluorescent dyes ; Fluorescent labelling ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Pyrrolo- and thiophenoperylenedicarboximides 4 and 7 were prepared by reductive cyclization of 1-nitroperylenedicarboximides 3 and 5 with phosphorous acid esters and sulfur, respectively. The imides 4 and 7 are highly fluorescent and are easily monofunctionalized by nucleophilic substitution reactions which makes them useful for fluorescent labeling.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 5
    ISSN: 0947-3440
    Schlagwort(e): Fluorescent dyes ; Pigments ; Perylenes ; Carboximides ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Perylene-3,4-dicarboximides 2 are obtained by a decarboxylizing condensation of moderately sterically hindered primary amines with perylene-3,4,9,10-tetracarboxylic 3,4:9,10-bisanhydride (3) in the presence of water. Perylene-3,4-dicarboxylic anhydride (4) is prepared by hydrolysis of the imides with KOH in tert-butyl alcohol. The anhydride may be condensed with any primary amine to the corresponding imide. The imides are highly fluorescent and very photostable dyes.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 467-468 
    ISSN: 0947-3440
    Schlagwort(e): Decarboxylation ; Carboxylic acids ; Fluorescence spectroscopy ; Perylenes ; Heterocycles ; Dyes ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Perylene-3,4-dicarboxylic anhydride (3) is prepared from technical grade perylene-3,4:9,10-tetracarboxylic anhydride (1) in 25% yield by a partial decarboxylation reaction using noncondensing amines. Perylene-3-carboxylic acid (4) and perylene-3,4-dicarboxylic imide (5) are prepared in the same way in yields of 24% and 76%, respectively, by a variation of the reaction conditions.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 1151-1153 
    ISSN: 0947-3440
    Schlagwort(e): Fluorescent dyes ; Perylenes ; Heterocycles ; Photosynthesis reaction center ; CD effects ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of a bifluorophoric perylene dye (4a) is described, in which the two chromophores are linked by a chiral binaphthyl unit. A strong exciton coupling of the two chromophores, a bathochromically shifted fluorescence and strong CD effects are observed. The structure of 4 is compared to the photosynthesis reaction center.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 529-535 
    ISSN: 0009-2940
    Schlagwort(e): Perylene dyes ; Hydrocarbons polycyclic ; Fluorescent dyes ; Fluorescent labelling ; Fluorescent tracer ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Synthesis of Nonsymmetrically Substituted Perylene Fluorescent DyesA general method for the preparation of perylene-3,4:9,10-tetracarboxdiimides 1 with two different substituents at the nitrogen atoms is described: The easily prepared symmetrical tetracarboxdiimides 1 (R1=R2) are transformed into carboxdiimide anhydrides 2 and condensed with primary amines to the corresponding tetracarboxdiimides 1 (R1 ≢ R2). Applications as fluorescent tracers in biochemistry and polymer chemistry are discussed.
    Materialart: Digitale Medien
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