ISSN:
1434-193X
Keywords:
Asymmetric synthesis
;
Lipases
;
Microdiprion pallipes
;
Pheromones
;
Pine sawfly
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
(1S,2S,6S,10R)- and (1S,2R,6R,10R)-1,2,6,10-tetramethyldodecyl propanoate (1 and 2), the components of the pheromone of Microdiprion pallipes, were synthesized from two chiral and nonracemic building blocks, (R)-3-tert-butoxycarbonyl-2-methylpropanoic acid (D) and (2R,6S)-7-acetoxy-2,6-dimethyl-1-heptanol (G), by employing lipase-catalyzed kinetic resolution in a later step.
Type of Medium:
Electronic Resource
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