ISSN:
0009-2940
Keywords:
Buckminsterfullerenes
;
Organodihydrofullerenes
;
Fullerene derivatives
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Controlled two-step nucleophilic hydroalkylations, hydroar-ylations as well as hydrostannylations of fullerene-60 (1) and fullerene-70 (2) lead to defined organodihydrofullerenes C60HR and C70HR. NMR investigations show that only one isomer of each organodihydrofullerene with Cs symmetry is formed. In all cases the addition takes place at a double bond separating two six-membered rings of the fullerene core. In this way a variety of organodihydrofullerenes also carrying functional groups have been synthesized.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19931260428
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