ISSN:
0009-2940
Keywords:
Organoaluminium compounds
;
Organogallium compounds
;
Organoindium compounds
;
Intramolecular base stabilization
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Intramolecularly stabilized four-coordinated organoaluminium, -gallium, and-indium compounds R2MC6H4CH2NR'2-(2) (1-7), Me2MCH2C6H4NMe2-(2) (8, 9), Me2MCH2C6H4CH2-NMe2-(2) (10, 11), and Me2GaC6H4NMe2 (12) have been synthesized from O -[(dialkylamino)methyl]phenyllithium, [O -(dimethylamino)phenyl]methyllithium, {O -[(dimethylamino)methyl]phenyl}methyllithium and O -(dimethylamino)phenyllithium, respectively. The 1H-, 13C—NMR, and mass spectra of the new compounds and the X-ray crystal structures of 2 and 7 are reported and discussed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901231103
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