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  • Articles: DFG German National Licenses  (2)
  • Micellar liquid phases  (1)
  • Polymer and Materials Science  (1)
  • 1
    Electronic Resource
    Electronic Resource
    A statistical study of the correlation between k′ or log k′ and log Pow for a group of benzene and naphthalene derivatives in micellar liquid chromatography using a C-18 column (1995)
    Springer
    Chromatographia 40 (1995), S. 185-192 
    Details
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Micellar liquid phases ; Octanol-water partition coefficient ; Benzene and naphthalene derivatives
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary It is shown that the logarithm of the capacity factor (log k′) for fifteen benzene and naphthalene derivatives in micellar liquid chromatography with forty nine different mobile phases generally correlates better with the logarithm of the octanol-water partition coefficient (log Pow) than the capacity factor (k′). Optimum conditions are established to obtain the best linear correlations of log k′-log Pow.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02272169
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Influence of the catalyst on the kinetics of a RIM formulation (1989)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 38 (1989), S. 237-248 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of three different catalysts [triethylendiamine (TD), stannous octoate (SO), and dibutylindilaurate (DBTDL)] and their blends (TD + SO and TD + DBTDL) on the kinetics of a RIM formulation, based on a high functionality polyether-polyol and a polymeric MDI, has been studied using the adiabatic temperature rise method and Fourier transform infrared spectroscopy. The synergism observed in the DBTDL/TD systems is explained by means of complex formation between the amine-based and metal-based catalysts. Infrared spectroscopy data support this complex formation. The SO/TD systems do not exhibit synergetic behaviour, being the reaction rate controlled by the metal catalyst which complexes the isocyanate group.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1989.070380204
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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