ISSN:
1588-2837
Keywords:
Oxidation
;
triphenylphosphine
;
vanadium oxytrichloride
;
solvent effect
;
mechanism
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract A kinetic study on triphenylphosphine oxidation with VOCl3 was carried out in CCl4 and THF. The different mechanisms were elucidated; oxygen was activated dissociatively on solid vanadium complex in CCl4, while oxygen was coordinated molecularly on soluble vanadium complex in THF.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010314800363
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