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  • Articles: DFG German National Licenses  (4)
  • POV measures  (2)
  • adducts  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Acta applicandae mathematicae 6 (1986), S. 47-62 
    ISSN: 1572-9036
    Keywords: 81M05 ; 83A05 ; Harmonic analysis ; POV measures ; relativistic stochastic phase space
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract Continuing some earlier work on the Galilei group, the spectral resolution of phase space representations of the Poincaré group is achieved by deriving all possible decompositions into irreducible representations corresponding to reproducing, kernel Hilbert spaces. Systems of covariance related to quantum measurements performed with extended test particles are analyzed, and questions of global unitarity discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Acta applicandae mathematicae 6 (1986), S. 1-18 
    ISSN: 1572-9036
    Keywords: 20C35 ; 81G20 ; 83A05 ; POV measures ; systems of covariance ; phase space representations of kinematical groups ; stochastic geometries
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In this paper we review the mathematical methods and problems that are specific to the programme of stochastic quantum mechanics and quantum spacetime. The physical origin of these problems is explained, and then the mathematical models are developed. Three notions emerge as central to the programme: positive operator-valued (POV) measures on a Hilbert space, reproducing kernel Hilbert spaces, and fibre bundle formulations of quantum geometries. A close connection between the first two notions is shown to exist, which provides a natural setting for introducing a fibration on the associated overcomplete family of vectors. The introduction of group covariance leads to an extended version of harmonic analysis on phase space. It also yields a theory of induced group representations, which extends the results of Mackey on imprimitivity systems for locally compact groups to the more general case of systems of covariance. Quantum geometries emerge as fibre bundles whose base spaces are manifolds of mean stochastic locations for quantum test particles (i.e., spacetime excitons) that display a phase space structure, and whose fibres and structure groups contain, respectively, the aforementioned overcomplete families of vectors and unitary group representations of phase space systems of covariance.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 38 (1992), S. 1391-1398 
    ISSN: 1572-8943
    Keywords: adducts ; complexes ; 8-hydroxyquinoline
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die hergestellten Addukte von [Mo(CN)8]3− und von [W(CN)8]3− mit 8-Hydroxyquinolin (Oxin) haben die allgemeine Formel K3[Mo(CN)8](C9H7ON)8·4H2O bzw. K3[W(CN)8](C9H7ON)6·3H2O. Die FTIR-Spektren beweisen die Gegenwart der (CN)- bzw. der Oxingruppen in den Adduktverbindungen durch die Peaks im Bereich 2047–2108 cm bzw. 1015–1461 cm−1. Die untere Region des FTIR-Spektrums zeigt die M=O Valenzschwingung, die obere Region (N-H) und (OH). Nichtkoordiniertes Wasser wird in diesen Addukten in einem einzigen Schritt bei 110°C abgegeben. Die Zersetzung der Adduktverbindungen beginnt bei 125°C und setzt sich in verschiedenen Schritten bis hin zu 850°C fort. Der zweite Schritt der Zersetzung wird durch die Abgabe von Oxinmolekülen beherrscht, wobei polymere Oxide der allgemeinen Formel K2OM2O5 (mitM= Mo oder W) als Pyrolyseprodukte erhalten werden.
    Notes: Abstract The adducts of [Mo(CN)8]3− and [W(CN)8]3− with 8-hydroxyquinoline (oxine) synthesized were of the type K3[Mo(CN)8]·(C9H7ON)8·4H2O and K3[W(CN)8]·(C9H7ON)6·3H2O. The FTIR spectra show the presence of the (CN) and oxine group in the adduct compounds through the peaks in the range 2047–2108 cm−1 and 1015–1461 cnf−1 respectively. The lower region of FTIR spectra show the M=O stretching while the higher range to v(N-H) and v(OH) modes. The uncoordinated water in these adducts was removed at around 110°C in a single step. The decomposition of adduct compounds starts from 125°C and continues to higher temperatures upto 850°C in different stages. The second stage of decomposition was predominant with the removal of oxine molecules with the formation of polymeric oxide of the type K2O·M2O5 (whereM=Mo or W) obtained as the pyrolysis product.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 46 (1996), S. 1763-1774 
    ISSN: 1572-8943
    Keywords: adducts ; complexes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The photoproduct of octacyanomolybdate(IV) and -tungstate(IV) with ethylenediamine and triethylenetetramine give complexes of the type K3[Mo(O2)(O)(OH)(C9H7ON)]·3C9H7ON I, K2[W(O2)(O) (C9H7ON)3] II and K3[Mo(CN)3(OH)4(C9H7ON)]·2C9H7ON·3H2O III with 8-quinolinol (oxine). The IR spectra of the complex III shows the presence ofv(CN) peaks in the range 2047–2108 cm−1 and oxine groupv(C-O) in the complex I, II and III in the range of 1100–1150 cm−1. The lower region of IR spectra shows the M=O stretching while the higher thev(N-H) andv(OH). Thermal studies show the removal of uncoordinated water at 131
    Type of Medium: Electronic Resource
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