ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Polymerization of cyclohexene oxide, especially the catalytic activity influenced by silanol structure, was examined by using an Al(acac)3-silanol compound catalyst. The catalytic activity increased as the acidity of silanol increased. It was prolonged by sterically hindered silanol compounds which prevented the silanol from self-condensation and from joining with the epoxide. In addition, the greater catalytic activity produced by intramolecular hydrogen-bonding silanol compounds is explained by the polymer effect.
Additional Material:
9 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1981.170191129
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