ISSN:
0044-2313
Keywords:
Phosphine Cobalt Carbonyl Complexes
;
Alkyl, Alkoxy Cobalt Carbonyls
;
Sulfur Dioxide
;
Organosilyl, Alkoxysulfinyl Phosphine Cobalt Carbonyl Complexes
;
Synthesis
;
IR, 1H NMR Spectra
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Sulfur Dioxide as Ligand and Synthon. IX. Reactions of Cobalt Carbonyls with Sulfur Dioxide - Synthesis and Characterization of Alkoxysulfinyl-Cobalt Carbonyl ComplexesReactions of phosphine substituted Co2(CO)8, (Ph2P-(CH2)n-PPh2: n = 1, dppm; n = 2, dppe; n = 3, dppp; n = 4, dppb), alkylcobalt carbonyls and alkoxycobalt carbonyls with sulfur dioxide have been investigated. The SO2 containing cobalt complexes are characterized by means of I.R., 1H-NMR, and mass spectra. Further on synthesis and properties of new alkoxysulfinylphosphine-cobalttricarbonyl complexes of the type ROS(O)Co(CO)3PR31 (R = Ph3Si, Me; R1 = Et, i-Pr, Ph) are described.
Notes:
Reaktionen von phosphinsubstituiertem Co2(CO)8, (Ph2P-(CH2)n-PPh2: n = 1, dppm; n = 2, dppe; n = 3, dppp; n = 4, dppb), Alkylcobaltcarbonylen sowie Alkoxycarbonyl-Cobaltcarbonylen mit Schwefeldioxid wurden untersucht. Die Charakterisierung der gebildeten SO2 enthaltenden Cobaltkomplexe erfolgte mit Hilfe der IR-, 1H-NMR- und Massenspektroskopie. Darüber hinaus werden Synthese und Eigenschaften neuer Alkoxysulfinyl-Phosphin-Cobalttricarbonyl-Komplexe des Typs ROS(O)Co(CO)3PR31 (R = Ph3Si, Me; R1 = Et, i-Pr, Ph) beschrieben.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19915920115
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