ISSN:
0020-7608
Keywords:
Computational Chemistry and Molecular Modeling
;
Atomic, Molecular and Optical Physics
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The electron mechanism of the nonequilibrium vibration excitation is considered in multiatom molecules with the condition that the bottleneck effect takes place. The quantum-statistical theory states that if the simplest enzyme reaction is proposed on the basis of the vibrational energy recuperation idea, the vibrons emitted in producing the free product and enzyme activate the first stage of the formation of the Michaelis-Menten complex and the multiphonon feedback mechanism is realized. Resulting solutions are applied to explain some biochemical and genetic effects.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/qua.560170210
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