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Matrix-assisted laser desorption mass spectrometry of oligodeoxythmidylic acids (1992)

Huth-Fehre, T. ; Gosine, J. N. ; Wu, K. J. ; [et al.]

New York, NY : Wiley-Blackwell

Rapid Communications in Mass Spectrometry 6 (1992), S. 209-213

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ISSN: 0951-4198

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Physics

Notes: Ferulic acid, sinapinic acid and 2,5-dihydroxybendoic acid (DHBA) have been tested as matrix materials for matrix-asserted laser desorption of the pure oligonucleotide pd(T)12 and a mixture of oligonucleotides pd(T)12 through pd(T)18 using pulsed 337 nm radiation combined with reflecting time-of-flight mass spectrometry. The three matrix materials are compared with respect to obtainable mass resolution, degree of fragmentation, and adduct formation, as well as the highest mass resolution.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/rcm.1290060312

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