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Metal(II) complexes and metal(II) salts ofN-carbamoylpyrazole: N,O and N,N coordination (1980)

Terheijden, Jos ; Driessen, Willem L. ; Groeneveld, Willem L.

Springer

Transition metal chemistry 5 (1980), S. 346-350

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ISSN: 1572-901X

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Summary Several new coordination compounds are reported withN-carbamoylpyrazole (Hcpz) as the ligand;viz. M(cpz)2 where M = CuII and NiII; M(Hcpz)Cl2 where M = MnII, CoII, CuII, ZnII and CdII; M(Hcpz)2Cl2 Where M = FeII, CoII and NiII: M(Hcpz)3(BF4)2 where M = FeII, CoII, NiII, ZnII and CdII; and Cu(Hcpz)2(BF4)2. In the salts, Hcpz is coordinated through the nitrogen atoms of the pyrazole ring and the nitrogen atom of the carbamoyl group. In the Hcpz complexes, coordination takes place through the nitrogen atom of the pyrazole ring and the oxygen atom of the carbamoyl group.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01396957

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