ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. The thermal decomposition of 1-trimethylsilyl-μ3-S,S-ethylenedithiolatohexacarbonyldiiron leading to the formation of trimethylvinylsilane, CO and FeS is accompanied by partial desilylation with the formation of ethylene and propylene. 2. The pyrolysis of the dithiolane diiron hexacarbonyl complex of trimethylvinylsilane in the presence of HCl proceeds with significant desilylation of the starting complex and formation of 1,1-dichloroethane, 1,1-dichloropropane, butanedithiol, and hexanedithiol.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00954115
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