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  • Digitale Medien  (2)
  • 1985-1989  (2)
  • 1988  (2)
  • Engineering  (1)
  • electrolytes  (1)
  • aqueous
Materialart
  • Digitale Medien  (2)
Erscheinungszeitraum
  • 1985-1989  (2)
Jahr
  • 1
    ISSN: 1572-8927
    Schlagwort(e): Borates ; thermodynamics ; electrolytes ; Harned cells
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Potentials for the cell without liquid juction $$H_2 ,Pt|B(OH)_3 (m_1 ),NaB(OH)_4 (m_2 ),MCl_2 (m_3 )|AgCl,Ag$$ with M=Ca2+ or Mg2+ are reported over a range of ionic strength at 5, 15, 25, 35, 45, and 55°C. Parameters of Pitzer's ion interaction treatment are determined for Ca(B(OH)4)2 and Mg(B(OH)4)2 by fitting to the cell results. Apparent association of alkaline earth borates to form the monovalent species CaB(OH) 4 + and MgB(OH) 4 + makes it necessary to use the extended β(2) form of the ion interaction treatment to represent the potentials reported here. Trace activity coefficients of calcium and magnesium borates are tabulated at various temperatures and ionic strengths. The association constants for ion pair formation implied by the values of β(2) for these salts are compared with ion pair formation constants available in the literature.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 26 (1988), S. 2305-2318 
    ISSN: 0029-5981
    Schlagwort(e): Engineering ; Engineering General
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Mathematik , Technik allgemein
    Notizen: This paper describes the way in which an unsymmetric block Lanczos algorithm can be employed for approximate eigensolutions or dynamic response solutions for large systems having arbitrary damping and/or repeated (or closely spaced) eigenvalues. To reduce a square, unsymmetric matrix which may have repeated eigenvalues to block-tridiagonal form, an unsymmetric block Lanczos algorithm is developed. Right and left Lanczos vectors, generated by the reduction process, are employed to define the reduced-order model based on a discrete analytical model of general linear, time-invariant dynamic systems. A special type of starting vector is also introduced, which automatically includes the static displacement. This reduced-order model is employed to compute approximate eigenvalues/vectors and dynamic responses of the original system. To verify the proposed algorithm, examples of an 8-DOF beam-rotor system are provided for eigensolutions and dynamic responses due to step and random external forces. These examples showed promising results, indicating that the proposed algorithm is worthy of further study.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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