ISSN:
0009-2940
Keywords:
1,4-Diborafulvenes, 1,4-dihydro-
;
Slipped triple-decker
;
Nickel complexes
;
platinum complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Complexation of 1,4-Dihydro-1,4-diborafulvenes with Ni(cod) and Pt(cod) Fragments*Reactions of the 1,4-diborapentafulvene derivatives 1 and 2a, b with M(cod)2 (M = Ni, Pt) yield the complexes [(η5-1)Ni-(cod)] (8), [(μ,η2η5-2a){Ni(cod)}2] (9a), [(μ,η2,η5-2b){Ni(cod)}2] (9b), and [(μ,η2,η5-2a){Pt(cod)}2] (10). Compounds 9 and 10 are the first examples of complexes with 2a, b as a μ,η2,η5-ligand. The X-ray structure analyses of 9b and 10 are described.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941271209
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