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  • Electronic Resource  (2)
  • 1995-1999  (1)
  • 1975-1979  (1)
  • Polymer and Materials Science  (2)
  • 1
    Electronic Resource
    Electronic Resource
    ESCA Analysis of Photodegraded Poly(ethylene terephthalate) Film Utilizing Gas Chemical Modification (1996)
    Chichester [u.a.] : Wiley-Blackwell
    Surface and Interface Analysis 24 (1996), S. 711-717 
    Details
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The degradation of the surface composition of poly(ethylene terephthalate) (PET) film by ultraviolet light was analysed by ESCA combined with gas chemical modification (GCM) techniques. A new approach for distinguishing phenolic hydroxyl and alcoholic hydroxyl groups was presented, which uses the difference in reactivity of trifluoroacetic anhydride to the phenolic group and to the alcoholic group. The carboxyl group was detected with trifluoroethanol. The ESCA-GCM results showed differences of the chemical composition of the light-facing side and the back side of the PET film. According to photodegradation mechanisms of PET reported by other researchers, carboxyl group formation suggested cleavage of the main chain of PET. The number of the phenolic carbon on the light-facing side corresponded to the existence of 16 phenolic groups per 100 monomeric units.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
  • 2
    Electronic Resource
    Electronic Resource
    Photoinduced charge transfer at the poly(N-vinylcarbazole) - tin oxide interface (1975)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 13 (1975), S. 1275-1284 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: An investigation of steady state and transient photoconductivity in films of poly-(N-vinylcarbazole) equipped with SnO2 and metal electrodes is described. The studies have shown that photoinduced charge transfer, leading to hole injection into the polymer film, takes place with photons of energy greater than 1.8-1.9 eV. Dark conductivity studies on samples equipped with grounded guard rings have shown that carriers originating in the bulk of the polymer film dominate the dark current when the metal electrode is at negative bias. Thermionic hole emission from the SnO2 electrode is not observed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1975.180130702
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
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