ISSN:
1040-0397
Keywords:
Amalgam electrode
;
cadmium
;
macrocyclic complexes
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The electrochemical oxidation of cadmium amalgam was studied in the nonaqueous solvents CH2Cl2, 1,2-C2H4Cl2 and propylene carbonate. Significant coordination effects were observed between the electrogenerated Cd(II) ions and 18-membered macromonocyclic ligands, each containing six Lewis bases heteroatoms: 18-O6, 18-S6, 18-N2O4, and 18-N6. The stoichiometries and the stabilities of the resulting complexes were determined. These stabilities increase from 18-O6 or 18-S6 to 18-N6.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/elan.1140040106
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