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  • Electronic Resource  (1)
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  • Electronic Resource  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Amalgam electrodes: Direct electrochemical generation of cadmium macrocyclic complexes (1992)
    Weinheim : Wiley-Blackwell
    Electroanalysis 4 (1992), S. 19-26 
    Details
    ISSN: 1040-0397
    Keywords: Amalgam electrode ; cadmium ; macrocyclic complexes ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrochemical oxidation of cadmium amalgam was studied in the nonaqueous solvents CH2Cl2, 1,2-C2H4Cl2 and propylene carbonate. Significant coordination effects were observed between the electrogenerated Cd(II) ions and 18-membered macromonocyclic ligands, each containing six Lewis bases heteroatoms: 18-O6, 18-S6, 18-N2O4, and 18-N6. The stoichiometries and the stabilities of the resulting complexes were determined. These stabilities increase from 18-O6 or 18-S6 to 18-N6.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/elan.1140040106
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