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Digitale Medien

Vinyl polymerization of acrylonitrile by the Ce(IV)-glucose redox system (1983)

Padhi, N. P. ; Singh, B. C.

Springer

Colloid & polymer science 261 (1983), S. 390-393

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ISSN: 1435-1536

Schlagwort(e): vinyl polymerization ; Ce(IV)-initiated polymerization ; polymerization by Ce(IV)-glucose redox system ; redox polymerization

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie , Maschinenbau

Notizen: Abstract Aqueous polymerization of acrylonitrile (M) initiated by the Ce(IV)-glucose (R) redox system has been studied under nitrogen in the temperature range of 30–40 °C. The rate of polymerization (Rp) is proportional to [M]2, [R] and inversely proportional to [Ce(IV)]. The rate of ceric ion disappearance is proportional to [R] and [Ce(IV)]. The end group in the polymer is characterised by IR spectra. A suitable kinetic scheme has been proposed and explained in the light of these experimental findings.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01418211

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