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Digitale Medien

Polymerisation von Vinylverbindungen in Gegenwart von Titan(III)-chlorid (1980)

Moszner, N. ; Hartmann, M.

New York, NY : Wiley-Blackwell

Journal für Praktische Chemie/Chemiker-Zeitung 322 (1980), S. 963-970

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Details

ISSN: 0021-8383

Schlagwort(e): Chemistry ; Organic Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Polymerization of Vinyl Compounds in the Presence of Titanium(III)ChlorideThe polymerization of styrene, acrylonitrile and some methacrylates initiated by a titanium(III) chloride dichloroacetic acid redox system was studied. The monomer selectivity of the polymerization in the presence of titanium(III) chloride was found to be affected by a reductive termination reaction. Titanium(III) chloride acts as a retarder in the polymerization of styrene initiated by azobisisobutyronitrile (AIBN). The polymerization of polar monomers like acrylonitrile, methyl, ethyl and propyl methacrylate by AIBN is inhibited by titanium(III) chloride.

Zusätzliches Material: 7 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/prac.19803220613

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