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Digitale Medien

The mass spectra of alkyl phenyl tellurides (1976)

Busse, P. J. ; Grigsby, R. A. ; Kolar, F. L. ; [weitere]

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 11 (1976), S. 640-643

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Details

ISSN: 0030-493X

Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The mass spectra of several alkyl phenyl tellurides, C6H5TeR (R = CH3, CD3, C2H5, n-C3H7, i-C3H7 and n-C4H9) have been studied with special emphasis on the fragmentation patterns involving cleavage of the alkyl and aryl tellurium-carbon bonds. Each compound exhibited intense parent ions. The rearrangement ions [C6H6Te]+⋅ and [C6H6]+⋅ were found in the spectra of phenyl ethyl and higher tellurides. Two other rearrangement ions [HTe]+ and [C7H7]+ were observed in the spectrum of each compound. Examination of the mass spectrum of phenyl methyl-d3 telluride demonstrated that the [HTe]+ ions derive hydrogen from the phenyl group.

Zusätzliches Material: 1 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/oms.1210110611

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