ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The thioacetanilide negative molecular ion (produced by secondary electron capture) is stable, but it fragments after collisional activation to yield [C6H5NH]- by cleavage α to the C=S grouping. The negative molecular ions of (substituted) o-nitrothioacetanilides undergo a series of extremely complex rearrangement reactions. For example, the molecular anion derived from o-nitro-N-methylthioacetanilide yields both acetate and thioacetate anions as major fragment ions.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210140208
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