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  • Electronic Resource  (7)
  • 1970-1974  (7)
Material
  • Electronic Resource  (7)
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 243 (1973), S. 468-470 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] We have investigated the cytology and function of the oenocytes in the desert locust Schistocerca gregaria. The animals used were fifth instar female larvae fed on bran and wheat seedlings and exposed to a day of 12 h (35 C) followed by a night of 12 h (25 C). The instar lasts about 9 days. The ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 3 (1971), S. 243-248 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NMR spectrum of benzaldehyde oriented in the nematic phase of a mixture of p-(p-ethoxyphenylazo)phenylheptanoate and p-(p-ethoxyphenylazo)phenylundecylenate is analysed. It is demonstrated that the data are inconsistent with models in which the aldehyde group freely rotates or has minimum energy when it is perpendicular to the ring plane. The barrier height to rotation, however, cannot be obtained, nor is it possible to discriminate between the two possible solutions in which the averaging planar forms do or do not reorient in the liquid crystal between successive internal rotations.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 4 (1972), S. 721-723 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NMR spectrum of benzotrifluoride dissolved in the nematic phase of n-(p-ethoxybenzylidene)-p'-n-butylaniline has been analysed, and the structure of the proton and fluorine skeleton has been determined. The height of the hindering potential to trifluoromethyl rotation cannot be measured. Due to the low accuracy of the determined F—F distance, no precise information about the anisotropy of the indirect coupling can be given.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 5 (1973), S. 137-139 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NMR spectrum of cis-2-butene partially oriented in a nematic phase has been analysed, and information about the geometry and the indirect spin-spin coupling constants has been obtained. Assuming the barrier of rotation of the methyl groups and other geometrical information from microwave studies, we obtained = 126 ± 2° and = 116.8 ± 0·6°. The angle that the CH3 rotation axis makes with the double bond was calculated to be 127·5 ± 0.4°; this value is closely linked with the assumed value of = 109°28′.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 6 (1974), S. 33-34 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NMR spectrum of 1-chloronaphthalene has been studied in the nematic phase of N-(p′-ethoxybenzylidene)-p-n-butylaniline. Ratios of interproton distances have been derived.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 3 (1971), S. 791-795 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NMR spectrum of phenol, dissolved in a nematic solvent, is explainable in terms of two averaging planar structures for each of which the principle axis of orientation in the ring is on the opposite side of the oxygen atom from the hydroxyl proton. External hydrogen bonding to the solvent seems to be an important factor in determining the orientation. The molecular structure obtained is compared with those found by microwave spectroscopy and X-ray diffraction.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 405-407 
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The NMR spectrum of pyrimidine has been studied in the nematic phase of 4-methoxy benzylidene-4-amino-α-methyl cinnamic acid-n-propyl ester at room temperature. The ratios of all the interproton distances are determined and found to differ significantly from those obtained from microwave data. The molecule, like other aromatics, is shown to orient preferentially with its plane in the direction of the magnetic field.
    Type of Medium: Electronic Resource
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