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  • Electronic Resource  (2)
  • 1970-1974  (2)
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  • Electronic Resource  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Chlorine-photosensitized oxidations of chloroethanes and chloroethylenes in the gas phase (1971)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 3 (1971), S. 89-96 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Long-chain chlorine-photosensitized oxidation has been observed in the gas phase at about 355°K for 1,1,2,2- and 1,1,1,2-C2H2Cl4, C2HCl5, and C2Cl4 but not for C2H6, 1,2-C2H4Cl2, 1,1,1-C2H3Cl3, C2H4, and 1,2-C2H2Cl2. This is shown to depend on the exothermicity of the dissociation of the chloroethoxy radicals which must be involved in each reaction system.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550030108
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Reaction of chlorine with bromine (1974)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 6 (1974), S. 395-400 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Different possible mechanisms for the gas phase reaction of formation of bromine chloride from bromine and chlorine are discussed. The rate of the reaction has been deduced from photometric measurements in conventional static reactors of surface-to-volume ratio ranging between 0.6 and 3 cm-1, at temperatures between 51 and 113°C. Experimental data show that (1) the observed reaction is predominantly heterogeneous, and (2) the homogeneous reaction must proceed by an atomic chain mechanism initiated by Br atoms.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550060309
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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