ISSN:
1573-8353
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The anhydride and dimethyl ester of 4, 5-(1-benzyl-1, 2, 3-triazoline)-3, 6-endohexahydrophthalic acid, having a triazoline ring with an exo-cis configuration, are synthesized by reaction of benzyl azide with the furan-maleic anhydride adduct. Opening of the triazoline ring under the action of hydrochloric and acetic acids takes place with the separation of nitrogen and formation of the chloro and acetoxy derivatives, respectively, unaccompanied by a Wagner-Meerwein type of rearrangement.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01168914
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