Electronic Resource
Springer
The European physical journal
26 (1993), S. 204-206
ISSN:
1434-6079
Keywords:
36.40.+d
;
81.10.Bk
;
35.20.Wg
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract Using a CO2 laser we have desorbed LiOH and NaOH from a solid target into an expanding inert gas jet pulse. Subsequently the beam was ionized by photons from a UV laser. Surprisingly, we observed in mass spectra metal water clusters and metal-hydride water clusters. For the metals M=Li, Na we find that the [M(H2O)n]+ peaks are dominant for small clusters, while for large clusters (n〉20) the [MH(H2O)n]+ peaks are dominant. This indicates that the clathrate (H2O)20 may play an important role in the formation of metallo-water clusters.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01429145
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