ISSN:
0009-2940
Keywords:
Ambiphilic coordination compounds
;
Tripod ligands
;
Triphosphane ligands
;
Tollens reaction
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Ambiphilic Tripod Complexes: Synthesis and Coordination Chemistry of Long-Chained Functionalized Tripod Ligands RC(CH2PPh2)3 with R - Pentyl or 8-NonenylTripod ligands RC(CH2PPh2)3 with R = pentyl (3a) and R = 8-nonenyl (3b) are accessible from the corresponding triols. By using appropriately selected activation procedures the triols 1a, b are transformed into the tripodal ligands 3a, b. In addition to their direct characterisation the tripod ligands 3a, b have been further structurally analysed by the syntheses and X-ray analyses of specific cobalt (4a) and iron (4b) coordination compounds. An interesting side result from the X-ray analysis of [(3b)Fe(NCCH3)3](BF4)2 (4b) is the organisation of its solid-state structure by the hydrophobic 8-nonenyl substituents in the ligand backbone.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270205
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