ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Polyfunctionalized N-Tensides. I. Nucleophilic Substitutions with Bischloronitrosocompounds. 1. Reactions with Amines, Mercaptans and Sodium AzideChloronitrosation of alkenes gives bischloronitrosocompounds 1, which react with amines to α-aminooximes (2 and 4), with mercaptans to α-alkylthiooximes 11, and with sodium azide to α-azidooximes 8. Reduction with LiAlH4 gives vicinal substituted diamines (6, 7, 10) from α-amino-or α-azidooximes (2, 4, 8) and β-alkylthioamines 13 from α-alkylthiooximes 11.The determination of E- or Z-configuration in the α-substituted oximes is discussed.
Additional Material:
8 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19783200310
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